By Julius Rebek Jr.

This monograph describes the habit of molecules restrained to small areas. The small areas are created by means of the self-assembly of modules into hole capsular buildings via hydrogen bonding; drugs assembled by way of metal/ligand binding or different forces usually are not incorporated. issues mentioned contain how meeting of tablets happens, how molecules get out and in of the tablets, new spatial preparations (stereochemistry) created within the tablets, and the altered shapes, interactions and reactivities of molecules held contained in the small areas. The descriptions emphasize molecular attractiveness phenomena and the point of view is that of actual natural chemistry.

The ebook is the 1st monograph to regard reversible molecular encapsulation. greater than 20 collage and institute teams all over the world interact during this learn, which represents the vanguard of job in molecular attractiveness and the actual natural chemistry of restricted molecules.

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37. Johnson DW, Hof F, Iovine PM, Nuckolls C, Rebek Jr J. (2002) Solid state and solution studies of a tetrameric capsule and its guests. Angew Chem Int Ed Engl 41, 3793–3796. 38. Metzger A, Lynch VM, Anslyn EV. (1997) A synthetic receptor selective for citrate. Angew Chem Int Ed Engl 36, 862–865. 39. Szabo T, O’Leary B, Rebek Jr J. (1999) Self-assembling sieves. Angew Chem Int Ed Engl 37, 3410–3413. 40. Lützen A, Renslo AR, Schalley CA, O’Leary BM, Rebek Jr J. (1999) Encapsulation of ion-molecule complexes: second-sphere supramolecular chemistry.

Kobayashi K, Yamanaka M. (2014) Self-assembled capsules based on tetrafunctionalized calix[4]resorcinarene cavitands. 1039/c4cs00153b. 49. Park YS, Paek K. (2008) Hydrazide as a new hydrogen-bonding motif for resorcin[4]arene-based molecular capsules. Org Lett 10, 4867–4870. 50. Aakeroy CB, Rajbanshi A, Desper J. (2011) Hydrogen-bond driven assembly of a molecular capsule facilitated by supramolecular chelation. Chem Commun 47, 11411–11413. 51. Huerta E, Metselaar GA, Fragoso A, et al. (2007) Selective binding and easy separation of C70 by nanoscale self-assembled capsules.

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